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PHY 418: Statistical Mechanics I
Prof. S. Teitel: stte@pas.rochester.edu ---- Spring 2024

Problem Set 10

Due Monday, April 29, uploaded to Blackboard by 11pm

  • Problem 1 [15 points]

    Consider a non-interacting gas of spin zero bosons, whose energy-momentum relationship is given by ε(p) = A|p|s, for some fixed positive numbers A and s. The dimensionality of the gas is the number d, i.e. the volume of the gas is V = Ld, for a system of length L. In the following parts, we are considering the behavior in the thermodynamic limit of V → ∞.

    a) [5 pts] For what values of s and d will there exist Bose-Einstein condensation at sufficiently low temperatures? In particular, show that for s=2 (non-relativistic massive particles) there is no Bose-Eisntein condensation in d=2 dimensions.

    b) [4 pts] For the case that there is Bose-Einstein condensation, write an expression that gives how the condensation temperature Tc depends on the total density of particles n, and how the condensate density no depends on temperature T.

    c) [4 pts] Show that the pressure is related to the energy by, p = (s/d)(E/V)

    d) [2 pts] Can a gas of photons in d = 3 undergo Bose-Einstein condensation?

  • Problem 2 [20 points]

    Consider a three-dimensional gas of N indistinguishable non-interacting spin zero bosons of mass m in an external isotropic harmonic potential U(r) = (1/2)mω02 |r|2, where r = (x, y, z). This might be taken as a model for bosons in a magnetic trap. The quantized single particle energy levels are given by ε(nx, ny, nz) = ℏω0 (nx + ny + nz + 3/2), where nx, ny, nz = 0, 1, 2, . . . are integers.

    a) [6 pts] Compute the density of states g(ε). The density of states is such that g(ε)dε is the number of single particle states between ε and ε+dε.

    Hint: You should try to do this the same way you found g(ε) in Problem Set 9 problem 3, but generalizing to 3D. You may assume that the thermal energy is much greater than the spacing between the energy levels, i.e. kBT >> ℏω0.

    b) [3 pts] What is the largest value that the fugacity z can take?

    c) [5 pts] Show that this system has Bose-Einstein condensation at sufficiently low temperature.

    d) [3 pts] Find the Bose-Einstein condensation temperature Tc as a function of the number of paricles N.

    e) [3 pts] Find how the number of particles N0(T) in the condensed state varies with temperature for T=0 to Tc.

  • Problem 3 [20 points]

    N Fermions A of spin 1/2 (i.e. gs=2) are introduced into a large volume V at temperature T. Two Fermions may combine to create a Boson with spin 0 (i.e. gs=1) via the interaction,

    A + A ↔ A2
    Creation of the molecule A2 costs energy εo > 0. At equilibrium, the system will contain NF Fermions and NB Bosons. Provide expressions from which the ratio NB/NF can be calculated, and perform the calculation explicitly for T=0. What would this (T=0) ratio be, if the particles were classical (i.e. quantum statistics could be neglected). Explain the difference.