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PHY 418: Statistical Mechanics I
Prof. S. Teitel stte@pas.rochester.edu ---- Spring 2013
February
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1
lecture 5
Extremum principles for free energies, Maxwell relations, response functions and relations between them
make-up lecture
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2
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3
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4
lecture 6
Curvature of free energies and stability requirements for response functions, kinetic theory of ideal gas, Maxwell velocity distribution
supplemental notes
Heat engines, thermodynamic efficiency, Carnot cycle
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5
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6
lecture 7
Ergodic hypothesis, statisitcal ensembles, density matrix, Liouville's theorem
HW #1 due
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7
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8
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9
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10
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11
lecture 8
Microcanonical ensemble, density of states and connection to entropy, entropy of the ideal gas and problem of extensivity
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12
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13
lecture 9
Entropy of mixing and Gibbs paradox, indistinguishable particles, the canonical ensemble and the canonical partition function
HW #2 due
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14
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15
lecture 10
Helholtz free energy and the canonical partition function, energy fluctuations, equivalence of canonical and microcanonical ensembles in the thermodynamic limit
make-up lecture
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16
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17
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18
lecture 11
Average energy vs most probably energy, Stirling's formula, factoring the canonical partition function for non-interacting objects, Maxwell velocity distribution revisited, the virial theorm
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19
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20
lecture 12
The equipartition theorem, elastic vibrations of a solid and the law of Dulong and Petit, paramagnetism of classical spins
HW #3 due
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21
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22
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23
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24
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25
lecture 13
The Curie law of paramagnetic susceptibility, a note about the proper choice of coordinates, entropy and information
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26
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27
lecture 14
Entropy and information, the grand canonical ensemble
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28
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