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Lecture Notes


PHY 418: Statistical Mechanics I
Prof. S. Teitel stte@pas.rochester.edu ---- Spring 2013

Lecture Notes

My hand written class lecture notes are being scanned and uploaded for you to view. Please be warned that these are the notes I prepare for myself to lecture from - they are not in general carefully prepared for others to read. I make no guarantees about their legibility, or that they are totally free of errors. I hope, nevertheless that you will find them useful. The lectures are uploaded as pdf files, so you will need Adobe Acrobat Reader in order to read them. You can download Acrobat Reader for free here.

The lecture note files correspond roughly to the material presented in a given day's lecture. But you may on occassion find the end of one day's lecture at the start of the file for the next day's lecture, so please look there if you think there might be something missing.

  • Lecture 0 - Sketching the history of statistical mechanics and thermodynamics (another such page here.)

  • Lecture 1 - Postulates of classical thermodynamics, entropy, temperature, pressure, chemical potential

  • Lecture 2 - Conditions for thermal, mechanical and chemical equilibrium, concavity of the entropy, equations of state

  • Lecture 3 - Euler relation, Gibbs-Duhem relation, entropy of the ideal gas, entropy maximum vs energy minimum principle, Legendre transformation

  • Lecture 4 - Legendre transformations, Helmholtz and Gibbs free energies, enthalpy, the grand potential, reservoirs

  • Lecture 5 - Extremum principles for free energies, Maxwell relations, response functions and relations between them

  • Lecture 6 - Curvature of free energies and stability requirements for response functions, kinetic theory of ideal gas, Maxwell velocity distribution

    Lecture 6 supplement - Heat engines, thermodynamic efficiency, Carnot cycle
  • Lecture 7 - Ergodic hypothesis, statisitcal ensembles, density matrix, Liouville's theorem

  • Lecture 8 - Microcanonical ensemble, density of states and connection to entropy, entropy of the ideal gas and problem of extensivity

  • Lecture 9 - Entropy of mixing and Gibbs paradox, indistinguishable particles, the canonical ensemble and the canonical partition function

  • Lecture 10 - Helholtz free energy and the canonical partition function, energy fluctuations, equivalence of canonical and microcanonical ensembles in the thermodynamic limit

  • Lecture 11 - Average energy vs most probably energy, Stirling's formula, factoring the canonical partition function for non-interacting objects, Maxwell velocity distribution revisited, the virial theorm

  • Lecture 12 - The equipartition theorem, elastic vibrations of a solid and the law of Dulong and Petit, paramagnetism of classical spins

  • Lecture 13 - The Curie law of paramagnetic susceptibility, a note about the proper choice of coordinates, entropy and information

  • Lecture 14 - Entropy and information, the grand canonical ensemble

  • Lecture 15 - The grand canonical partition function and the grand potential

  • Lecture 16 - Fluctuations in the grand canonical ensemble, non-interacting particles, chemical equilibrium

  • Lecture 17 - A gas in equilibrium with a surface of absorption sites, quantum statistical ensembles, density matrix operator

  • Lecture 18 - Quantum microcanonical, canonical, and grand canonical ensembles, quantum harmonic osciallator at temperature T, Bose-Einstein and Fermi-Dirac statistics, Pauli exlusion principle, occupation number representation

  • Lecture 19 - Density matrix for two non-interacting particles, quantum correlations as an effective classical pair interaction, N-particle partition function in the position-space basis, partition functions for non-interacting quantum ideal gas

  • Lecture 20 - Classical partition function in the occupation number representation, average occupation number, the classical vs quantum limits of the ideal gas

  • Lecture 21 - The quantized harmonic oscillator as bosons, the Debye model for the specific heat of a solid, black body radiation

  • Lecture 22 - The quantum ideal gas, standard functions, pressure, density, energy, the leading correction to the classical limit

  • Lecture 23 - The degenerate Fermi gas, ground state energy, the Sommerfeld expansion, chemical potential at finite temperature

  • Lecture 24 - Specific heat of degenerate Fermi gas, Pauli paramagnetism

  • Lecture 25 - The ideal Bose gas, Bose-Einstein condensation in an ideal gas of free bosons

  • Lecture 26 - Classical spin models, constant magnetization vs constant magnetic field ensembles, broken symmetry and the possibility for a phase transition in the thermodynamic limit, Ising phase diagram

  • Lecture 27 - Mean-field solution of the Ising model, critical exponents

  • Lecture 28 - Mean-field solution and critical exponents continued, Maxwell construction, exact solution of the one dimensional Ising model