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PHY 418: Statistical Mechanics I
Prof. S. Teitel: stte@pas.rochester.edu ---- Spring 2026
Problem Set 7
Sunday, April 12, uploaded to Blackboard by 11:59pm
- Problem 1 [15 points total]
Consider photons of a given energy ε = ℏω. As will be discussed in Notes 3-6, photons of frequency ω can be thought of as excitations of a quantized harmonic oscillator of frequency ω (the transverse EM wave at frequency ω), where excitation to level n of the oscillator corresponds to having n photons. Using the results at the end of Notes 3-1, show the following:
(a) Using Eq. (3.1.38) of Notes 3-1 for the probability Pn to be excited to level n of the harmonic oscillator (and so the probability to have n photons), show that the fluctuation in the number of photons is,
<n2> - <n>2 = - (1/ε) (d<n>/dβ) where β = 1/kBT
(b) Using the forumula for the equilibrium value of <n>, apply the above result to determine the relative fluctuation in the number of photons
[<n2> - <n>2]/<n>2
Is this large or small?
- Problem 2 [15 points]
Consider a point particle of mass m attached to a harmonic spring with spring constant κ=mω02. The particle moves in only one dimension given by the coordinate x. The rest position of the particle (when the spring in unstretched) is at x=0. The particle is in equilibrium at temparature T.
Assuming that the particle behaves quantum mechanically, compute the root-mean-square fluctuation in the position of the particle, Δx = (〈x2〉 - 〈x〉2)1/2.
Hint: recall that for the quantum harmonic oscillator, the expected value of the kinetic energy equals the expected value of the potential energy (this is the quantum virial theorem).
Show that in the limit kBT ≫ ℏω0 you recover the answer for a classical particle.
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